谁能帮我翻译一下,这两段内容。很简单的。

谁能帮我翻译一下,这两段内容。很简单的。不好意思,改道学[wiki]化学[/wiki]的,没基础。
All sensitive materials were transferred under inert atmosphere conditions, using a dry box or Schlenk apparatus. Solvents were dried by reflux over Na or H2Ca in an Ar atmosphere. All starting materials were [wiki]pu[/wiki]rified by crystallization or distillation under low pressure.

General Procedure for the Titanium-Induced Couplings. TiCl3 (1.03g, 6.7 mmol) and 1.5 g of Zn-Cu coupleb were covered with 20 mL of dry solvent . The mixture was refluxed for 1 h with effective stirring under Ar atmosphere. .A solution of 3.35 mol of the carbonyl compound in 5 mL of dry solvent was added at once, and refluxing was continued for the amount of time indicated in Table I. To the reaction mixture was added 25 g of silica gel, and the solvent was removed under vacuum, the residue being incorporated at the top of a silica gel column. Stilbenes were eluted with CH2Cl2, normally giving crystalline compounds.


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最新回复

  • wcrxy (2008-10-03 21:05:56)

    你可以使用金山词霸~这样就没有问题了~
  • meteor_121 (2008-10-03 23:06:57)

    QUOTE:

    原帖由 wcrxy 于 2008-10-3 21:05 发表
    你可以使用金山词霸~这样就没有问题了~
    我使用灵格斯翻译家,但是有些语言组织不如天天看化学的来的顺,就来问问
  • wenkine (2008-10-03 23:58:16)

    所有敏感的原料都使用[wiki]干燥[/wiki]箱或希莱克仪器在惰性[wiki]气体[/wiki]氛围中操作,溶剂采用[wiki]金属钠[/wiki]或[wiki]氢[/wiki]化钙在[wiki]氩气[/wiki]保护下回流干燥。起始原料均经过[wiki]结晶[/wiki]或低压蒸馏纯化。
    [wiki]钛[/wiki]诱导结合反应的常规过程
    三[wiki]氯[/wiki]化钛(1.03克,6.7毫摩尔)和1.5克[wiki]锌[/wiki]铜合金加入20毫升干燥溶剂浸没,混合物在氩气保护中搅拌回流1小时,立即加入3.35摩尔的羰基化合物(用5ml干燥溶剂溶解),继续回流,回流时间见表1。反应混合物加入25克[wiki]硅[/wiki]胶,减压蒸除溶剂,剩余物置硅胶柱顶部,用二氯[wiki]甲烷[/wiki]洗脱1,2-二[wiki]苯[/wiki]乙烯,正常得到结晶化合物。
  • meteor_121 (2008-10-04 01:33:49)

    QUOTE:

    原帖由 wenkine 于 2008-10-3 23:58 发表
    所有敏感的原料都使用干燥箱或希莱克仪器在惰性气体氛围中操作,溶剂采用金属钠或氢化钙在氩气保护下回流干燥。起始原料均经过结晶或低压蒸馏纯化。
    钛诱导结合反应的常规过程
    三氯化钛(1.03克,6.7毫摩尔)和1.5克锌铜合 ...
    非常感谢,呵呵